High pressure study on induced SAphases in binary liquid crystal mixtures

Abstract
Binary mixtures of terminal polar and non-polar liquid crystals exhibiting induced smectic phases are studied under high pressure. For terminal polar compounds with smectic phases, there are two types of T, x phase diagrams known up to now. Diagrams with a nematic gap between the induced phase and the smectic phase of the terminal polar compound and diagrams with an uninterrupted miscibility of the smectic phases. We find a continuous transformation between these phase diagrams with pressure. At a certain pressure, the phase transition lines form a cross separating two nematic and two smectic phases.