The synthesis of alkenes from carbonyl compounds and carbanions ? to silicon. Stereoselective synthesis of 1-trimethylsilylbuta-1,3-dienes
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 969-970
- https://doi.org/10.1039/c39820000969
Abstract
Reactions of aldehydes with the 1,3-bis(trimethylsilyl)propenyl anion in the presence of magnesium bromide or trimethyl borate give stereoselectively the alcohols (2) which can be transformed stereospecifically to either (1E,3E)- or (1E,3Z)-1-trimethylsilylbuta-1,3-dienes.Keywords
This publication has 0 references indexed in Scilit: