Synthesis and cation complexing of N,N′-bridged bis-(1,4,7-trioxa-10-azacyclododecanes)

Abstract
Two molecules of monoaza-12-crown-4 can be linked through nitrogen in one step by direct double alkylation; the resulting bis-crown aminoethers give intramolecular alkali cation sandwich complexes which are particularly strong when the bridge is –CH2CH2– and the cation is sodium.

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