A non-linear truncation scheme for the Ornstein-Zernike equation for dipolar fluids
- 1 November 1982
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 47 (4) , 881-896
- https://doi.org/10.1080/00268978200100662
Abstract
A non-linear truncation method is proposed to represent the solution of the Ornstein-Zernike equation for dipolar fluids in terms of a finite number of angular projections. This method, which becomes exact at low densities, can be applied to the Percus-Yevick and hypernetted chain closures, and has the potential to study angular projections beyond the usual three angular projections that arise in the mean spherical approximation. Some numerical results for the hypernetted chain closure for hard sphere dipolar fluids will be given.Keywords
This publication has 13 references indexed in Scilit:
- The statistical mechanics of ion-dipole-tetrahedral quadrupole mixturesMolecular Physics, 1981
- On incorporating the second dielectric virial coefficient into theories which omit itMolecular Physics, 1981
- Integral equation approximations for dipolar fluidsMolecular Physics, 1979
- New self-consistent approximations for ionic and polar fluidsThe Journal of Chemical Physics, 1977
- Charged hard spheres in a uniform neutralizing background using ‘mixed’ integral equationsMolecular Physics, 1976
- Perturbation theory for the angular correlation functionMolecular Physics, 1974
- Invariant expansion III: The general solution of the mean spherical model for neutral spheres with electostatic interactionsThe Journal of Chemical Physics, 1973
- Invariant Expansion. II. The Ornstein-Zernike Equation for Nonspherical Molecules and an Extended Solution to the Mean Spherical ModelThe Journal of Chemical Physics, 1972
- Invariant Expansion for Two-Body Correlations: Thermodynamic Functions, Scattering, and the Ornstein—Zernike EquationThe Journal of Chemical Physics, 1972
- Exact Solution of the Mean Spherical Model for Fluids of Hard Spheres with Permanent Electric Dipole MomentsThe Journal of Chemical Physics, 1971