Chemistry of the silylamines. III. Condensation of silylamines with silylesters
- 1 January 1961
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 80 (8) , 819-824
- https://doi.org/10.1002/recl.19610800803
Abstract
The conditions under which a series of trimethylsilylesters of the type magnified image , where R=H, CH3, CF3, and C6H5, condense with a number of trimethylsilylamines to form hexamethyl‐disiloxane and an organic amide were investigated. The nature of the R group in the silylester appreciably affected the relative ease of condensation. Addition of an acid catalyst to the reaction system was observed to increase the relative rate of the reaction.Funding Information
- Silicones Division of Union Carbide Corporation
- Lowell Technological Institute Research Foundation
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