Synthesis of sulphines from aliphatic dithioesters and their rearrangement to dithioperoxyesters
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 390-391
- https://doi.org/10.1039/c39880000390
Abstract
Aliphatic dithioesters react with m-chloroperbenzoic acid to give selectively sulphines, with kinetic preference for the (E)-isomer. Rearrangement to dithioperoxyesters occurs at ambient temperature.Keywords
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