Reactions ofn6-o-Dichlorobenzene-n5-cyclopentadienyliron Cation with Anions from Nitroalkanes
- 1 January 1986
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 16 (8) , 1103-1107
- https://doi.org/10.1080/00945718608071384
Abstract
Treatment of the n6-o-dichlorobenzene-n 5-cyclopentadienyliron hexafluorophosphate with 3 molar equivalent of K2CO3 in nitroethane or nitromethane gives corresponding o-ClC,6H4 CH(R)NO2 FeCp+PF6 − (R = CH3 or H) complexes in excellent yields.Keywords
This publication has 5 references indexed in Scilit:
- Synthesis and characterization of η6-acetophenone-η5-cyclopentadienyliron hexafluorophosphateInorganica Chimica Acta, 1986
- Arylation of enolate anions with (.eta.6-chlorobenzene)(.eta.5-cyclopentadienyl)iron(II) hexafluorophosphateOrganometallics, 1986
- (Tropone)- and (tropothione)iron complexes from ring expansion reactionsOrganometallics, 1984
- Synthesis of some heterocyclic systems from nucleophilic substitution reactions with η6-o-dichlorobenzene-η5-cyclopentadienyliron hexafluorophosphateJournal of Heterocyclic Chemistry, 1982
- Phenylation of carbanions by .pi.-(chlorobenzene)chromium tricarbonylJournal of the American Chemical Society, 1974