Internal Cation Mobilities in Molten (Li, Ag)NO3 and (K,Ag)NO3 Remeasured by the Klemm Method
Open Access
- 1 June 1992
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung A
- Vol. 47 (6) , 781-787
- https://doi.org/10.1515/zna-1992-0611
Abstract
Internal mobility ratios bLi/bAg and bK/bAg in molten (Li,Ag)NO3 and (K,Ag)NO3 have been measured by Klemm’s countercurrent electromigration method. From these and available data on the densities and conductivities the internal mobilities have been calculated. The present experiments yielded more accurate data than previous ones using other methods. Over the investigated range of concentration and temperature, bAg is greater than bu or bK. The results are discussed together with earlier ones obtained for (Na, Ag)NO3 .Keywords
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