Infra-Red Spectrum of Polyatomic Molecules XVI. Methyl-d3-Chloride and Methyl-d3-Bromide
- 1 November 1942
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 10 (11) , 664-668
- https://doi.org/10.1063/1.1723640
Abstract
Methyl‐d3‐chloride and methyl‐d3‐bromide have been synthesized, their infra‐red spectrum in the range from 2.8 to 18μ measured, and a complete assignment of the fundamental frequencies has been given. A modified valence‐type potential function including two interaction terms fits the fundamental frequencies of the four molecules CH3Cl, CD3Cl, CH3Br, and CD3Br to within one percent.Keywords
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