Spherical tensor theory of long-range interactions in a system ofNarbitrary molecules including quantum-mechanical many-body effects
- 10 December 1986
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 59 (5) , 1097-1111
- https://doi.org/10.1080/00268978600102611
Abstract
In the previous two papers of this series we have applied the spherical tensor formalism to the perturbation treatment of long-range anisotropic forces in a collection of N molecules. In this paper we derive the compact formulas for all categories of the isotropic pairwise additive as well as pair wise non-additive interaction energies which occur in the first three orders of the perturbation theory of long-range forces between N arbitrary molecules. In this way the most important types of the isotropic induction and dispersion pairwise non-additive interactions are taken into account and clearly described.Keywords
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