Abstract
Interactions between copolypeptides containing Glu and Tyr residues and polynucleotides can be mediated through divalent metal ions such as Zn2+ and Cu2+. Circular dichroism studies show that the binding of metal ion – polypeptide complexes to poly(A) induces an unstacking of adenine bases. Fluorescence investigations demonstrate that Tyrosine – Adenine interactions result from the formation of ternary complexes polypeptide-Zn2+ -polynucleotide.

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