Solid state 31P n.m.r. spectroscopy of surface-attached triosmium clusters
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 938-941
- https://doi.org/10.1039/c39860000938
Abstract
Whilst the 31P n.m.r. spectra of H2Os3(CO)10L′ and Os3(CO)11L′{L′= PPh2[CH2]2Si(OEt)3} bound to silica are consistent with simple immobilisation, that of materials reported to contain H2Os3(CO)9L′ are inconsistent with this structure.Keywords
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