Structure of a fluid interface near the critical point
- 1 July 1988
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 38 (1) , 567-570
- https://doi.org/10.1103/physreva.38.567
Abstract
The structure of the liquid-liquid interface of three very different mixtures (carbon disulfide+methanol, methanol+cyclohexane+deuterated cyclohexane, and ) has been studied using ellipsometry in the reduced temperature range . Although the elliptical thickness varies by an order of magnitude between these mixtures, the data from all three mixtures can be scaled to the same universal constant by a combined meanfield plus capillary-wave model of the interface. The universal constant determined experimentally is significantly less than the theoretical value.
Keywords
This publication has 15 references indexed in Scilit:
- Ellipsometric study of the surface of simple liquidsPublished by Elsevier ,2002
- Universal amplitude ratios and the interfacial tension near consolute points of binary liquid mixturesThe Journal of Chemical Physics, 1986
- Effect of capillary waves on surface tensionPhysical Review A, 1986
- Interfacial tension of fluids near critical points and two-scale-factor universalityPhysical Review A, 1985
- Light scattering from liquid surfaces: Ellipsometric coefficientPhysical Review A, 1982
- Electric and magnetic susceptibilities for a fluid-fluid interface; The ellipsometric coefficientPhysica A: Statistical Mechanics and its Applications, 1981
- Structure and Free Energy of the Interface between Fluid Phases in Equilibrium near the Critical PointThe Journal of Chemical Physics, 1969
- Interfacial Density Profile for Fluids in the Critical RegionPhysical Review Letters, 1965
- Free Energy of a Nonuniform System. I. Interfacial Free EnergyThe Journal of Chemical Physics, 1958
- EQUILIBRIA IN THE SYSTEMS CARBON DISULFIDE:METHYL ALCOHOL, AND CARBON DISULFIDE:ETHYL ALCOHOL.1Journal of the American Chemical Society, 1922