The Decomposition of Transition Metal Tetrafluoroborates by some strong Base Ligands
- 1 March 1973
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 2 (4) , 323-324
- https://doi.org/10.1080/00958977308072995
Abstract
Some transition metal complexes of triethylene-diamine (TED, I) and quinuclidine (Q, II) have been reported.1–5 Recently we treated I and II with metal bistetrafluoroborates (M=Co2+, Ni2+, and Cu2+) which have not been studied yet, and postulated that pure coordination complexes might be obtained. However, evidence for the existence of 1:1 adducts such as C6H12N2:BF3 (III) and C7H13N:BF2 (IV) in treatment of I and II with metal bistetrafluoroborates has now been found. We wish to describe our results concerning formation of these two new 1:1 adducts in this letter.Keywords
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