Correlated motion of 2 particles in a fluid
- 1 May 1988
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 64 (1) , 97-109
- https://doi.org/10.1080/00268978800100093
Abstract
We derive a generalized Langevin equation for the simultaneous motion of two structureless particles (solute molecules) in a fluid. The resulting equations contain, in addition to the usual self memory integral term, a cross memory (or solvent-mediated drag) term which is a time-dependent generalization of the so-called hydrodynamic interaction. The cross memory function is expressed explicitly in terms of velocity cross correlation functions and may thus be evaluated numerically in molecular dynamics experiments.Keywords
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