Selective C−O Bond Cleavage of Vinyl Ethers with Cp*₂Sm(thf)_n Leading to Vinylsamarium or Enolate Complexes

This publication has 7 references indexed in Scilit:

• Activation of a CO bond by reaction of a tris(cyclopentadienyl)lanthanide complex with an alkali metal in dimethoxyethane (DME); crystal structures of [Ndη-C5H3(SiMe3)2-1,32(μ-OMe)2Li(DME)] and [{Ce(η-C5H3tBu2-1,3)2(μ-OMe)2]
  Journal of Organometallic Chemistry, 1995
• Generation of allenic samarium complexes from propargylic ethers and (C5Me5)2Sm(thf)2, and their electrophilic trapping
  Tetrahedron Letters, 1995
• A facile generation of organosamariumη3-allyl complexes by reductive cleavage of allylic ethers with (C5Me5)2Sm(THF)n
  Tetrahedron Letters, 1995
• Organolanthanide-induced carbon-carbon bond formation. Preparation and properties of monomeric lanthanide aldolates and enolates
  Organometallics, 1992
• Reactivity of samarium complex [(C5Me5)2Sm(.mu.-H)]2 in ether and arene solvents. X-ray crystal structures of the internally metalated complex (C5Me5)2Sm(.mu.-H)(.mu.-CH2C5Me4)Sm(C5Me5), the benzyl complex (C5Me5)2Sm(CH2C6H5)(THF), and the siloxide complex [(C5Me5)2Sm(THF)]2(.mu.-OSiMe2OSiMe2O)
  Organometallics, 1991
• Conformational study of N-substituted adenines by dynamic proton NMR: relatively high barrier to rotation about C6-N6 in N3,N6-disubstituted adenines
  The Journal of Organic Chemistry, 1990
• Organometallic compounds of the lanthanides. 36. Bis(pentamethylcyclopentadienyl) halide and alkyl derivatives of the lanthanides
  Organometallics, 1986