Conformational isomerism of phenolic procyanidins: preferred conformations in organic solvents and water
- 1 January 1997
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 5,p. 1035-1044
- https://doi.org/10.1039/a605592c
Abstract
NMR studies of catechin-(4α→8)-epicatechin (1) and catechin-(4α→8)-catechin (2) provided complete assignment of the proton and carbon resonances for both the more extended and compact conformers in the free phenolic form. When 1 is in organic solvents, the more extended rotamer is preferred over the more compact roKeywords
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