A new synthesis of macrocyclic lactones by rearrangement of 2-hydroxyalkyl-2-phenylsulphonylcycloalkanones

1 January 1981

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 21,p. 1123-1124
https://doi.org/10.1039/c39810001123

Abstract

2-Hydroxyalkyl-2-phenylsulphonylcycloalkanones undergo base-catalysed isomerisation into phenylsulphonyl-lactones with incorporation of the side-chain into the ring.

Keywords

MACROCYCLIC
NEW SYNTHESIS
CATALYSED
REARRANGEMENT
UNDERGO
SIDE
ISOMERISATION
PHENYLSULPHONYLCYCLOALKANONES
HYDROXYALKYL

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