On the possibility of complete condensation shock waves in retrograde fluids

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Abstract
Shock discontinuities for which the upstream state is vapour and the downstream state is liquid are considered. The possibility of such shock waves is associated with a large number of molecular degrees of freedom: it is necessary that the ideal-gas specific heatcv[ges ] 24Rat the critical temperature, a condition which is met by several common fluids. Shock properties are found from a corresponding-states thermodynamic model and from several calculations based on data for particular fluids. Condensation shock waves satisfy the usual stability conditions and should be found in laboratory experiments.

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