Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [{Co(phen)2}2V6O17]n and [{Cu(phen)2}4V10O29]·6H2O
- 1 January 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 1817-1818
- https://doi.org/10.1039/b005880g
Abstract
Two complexes, [{Co(phen)2}2V6O17]n 1 and [{Cu(phen)2}4- V10O29]·6H2O 2, have been hydrothermally synthesized; X-ray crystallography shows that 1 consists of one-dimensional stepped chains built up from covalently linked {V6O17}n 4n chains and [Co(phen)2]2+ fragments while 2 is composed of a discrete V10O29 8 cluster covalently attached to four [Cu(phen)2]2+ fragments.Keywords
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