Vibrational Spectrum of Bromotrifluoroethylene

Abstract
The infrared spectrum of gaseous bromotrifluoroethylene F2C:CFBr has been investigated in the range 2—52μ. The assignment of fundamentals parallels that for chlorotrifluoroethylene very closely. The planar vibrational frequencies in cm—1 are 1783(ν CC), 1330(ν CF), 1203(ν CF), 1027(ν CF), 659(ν CBr), 510(δ CF2), 370(δ CFBr), 311(ρ CF2), 160(ρ CFBr), while the out‐of‐plane modes are assigned 538(β CF2), 355(β CFBr), and 150(τ). A table of thermodynamic functions for the ideal gas is given.

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