Diastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4′-dimethyl-2,2′-bipyridine)iron(II)
- 18 September 1998
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 37 (17) , 2379-2380
- https://doi.org/10.1002/(sici)1521-3773(19980918)37:17<2379::aid-anie2379>3.0.co;2-c
Abstract
Two configurationally stable, chiral anions (TRISPHAT, 1) behave as efficient hosts that control the configuration of a configurationally labile iron(II) complex as the guest with high diastereoselectivity (>96 % de) upon ion pairing. The diastereoselectivity increases with decreasing solvent polarity.This publication has 0 references indexed in Scilit: