Photochemistry of βγ-epoxy ketones: photoisomerization of 2,2,4,4-tetraramethyl-7-oxabicyclo[4,1,0]heptan-3-one
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 881-882
- https://doi.org/10.1039/c39730000881
Abstract
Irradiation of 2,2,4,4-tetramethyl-7-oxabicyclo-[4,1,0]heptan-3-one does not lead to photodecarbonyl-ation, but rather photoisomerization occurs to give 2,2-dimethyl-4-(2-methylpropenyl)butanolide and 2,2,6-tri-methyl-4-oxohept-5-enal.Keywords
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