Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal–magnesium–alkoxide–diisopropylamides
- 3 May 2002
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 1176-1177
- https://doi.org/10.1039/b202549c
Abstract
A series of composite lithium– or sodium–magnesium–alkoxide–diisopropylamides of general formula [{MMg[N(Pri)2]2OR}2] (where M = Li, R = Octn; M = Na, R = Bun or Octn), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.Keywords
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