Chiral recognition in the Michael addition reaction between lithium N-3,4-dimethoxybenzyl-α-methylbenzylamide and the chiral iron crotonoyl complex [(C5H5)Fe(CO)(PPh3)(COCHCHMe)]
- 1 January 1990
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1554-1555
- https://doi.org/10.1039/c39900001554
Abstract
Chiral recognition in the Michael addition reaction between lithium N-3,4-dimethoxybenzyl-α-methylbenzylamide and the chiral iron crotonoyl complex [(C5H5)Fe(CO)(PPh3)(COCHCHMe)](matched pair R+R, S= 15) allows the kinetic resolution of the latter.Keywords
This publication has 7 references indexed in Scilit:
- Assignment of the absolute configuration to winterstein's acid, R-3-dimethylamino-3-phenyl propionic acid, by the asymmetric synthesis of homochiral (S)-(+)-ethyl 3-dimetylamino-3-phenyl propionateTetrahedron: Asymmetry, 1990
- Kinetic ResolutionPublished by Wiley ,1988
- Enantioselective synthesis of .beta.-amino esters through high pressure-induced addition of amines to .alpha.,.beta.-ethylenic estersJournal of the American Chemical Society, 1986
- Synthesis and Characterisation of E and Z α,β-Unsaturated Acyl Complexes [(η5-C5H5)Fe(CO)(PPh3)(COCH=CHR)] (R=H, Me, Et, -Bu, -Bu, Ph, vinyl,2-furyl)Tetrahedron, 1986
- The asymmetric synthesis of β-lactamsTetrahedron, 1986
- Synthesis and absolute configuration of the optically active forms of 2-[bis(2-chloroethyl)amino]-4-methyltetrahydro-2H-1,3,2-oxazaphosphorine 2-oxide (4-methylcyclophosphamide)The Journal of Organic Chemistry, 1977
- Asymmetric syntheses of .BETA.-amino acids by the addition of chiral amines to C=C double bonds.CHEMICAL & PHARMACEUTICAL BULLETIN, 1977