Reversible carbonylation of dialkylbiscyclopentadienylzirconium(IV): synthesis and structure of π-acyl derivatives of zirconium and X-ray structure of biscyclopentadienyl(π-acetyl)methylzirconium
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 522-523
- https://doi.org/10.1039/c39760000522
Abstract
Dimethyl- and dibenzyl-biscyclopentadienylzirconium(IV) react reversibly with carbon monoxide at atmospheric pressure giving the corresponding stable alkyl-acyl derivatives; the X-ray structure of the methyl derivatives shows the acyl group acting as a three-electron donor ligand.Keywords
This publication has 0 references indexed in Scilit: