Isotopic study of the temperature-programmed desorption of oxygen from silver
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 78 (1) , 143-146
- https://doi.org/10.1039/f19827800143
Abstract
The properties of oxygen adsorbed on silver were studied by a temperature-programmed desorption technique using an isotopic-tracer method. Oxygen adsorbates desorbed to form a well-defined single peak with a maximum at ca. 573 K. On the basis of the isotopic distribution during desorption and the surface coverage of the adsorbed oxygen, molecular and atomic oxygen adsorbates and embedded oxygen species are suggested to exist on or in the silver. The latter species can easily exchange its position with the atomic adsorbates.Keywords
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