Synthesis and X-ray crystal structure of the novel cluster anion [Rh12H(N)2(CO)23]3–; an irregular metallic array containing two interstitial nitrogen atoms
- 1 January 1986
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1742-1744
- https://doi.org/10.1039/c39860001742
Abstract
The anion [Rh12H(N)2(CO)23]3–, obtained by alkaline pyrolysis of [Rh6N(CO)15]–, contains a novel irregular dodecanuclear metallic skeleton which shows a trigonal-prismatic and a distroted square-antiprismatic hole occupied by two encapsulated nitrogen atoms.Keywords
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