Power-law behavior in the viscosity of supercooled liquids
- 1 August 1986
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 34 (3) , 1835-1840
- https://doi.org/10.1103/physrevb.34.1835
Abstract
We present experimental results on the viscosity of supercooled aqueous solutions of lithium chloride. The viscosity scales as (T- with μ=-2.08 over a large temperature range. Data on other systems show that both the power-law behavior and the approximate value of the exponent μ are typical for a wide variety of fluids. The region of power-law behavior occurs at much higher temperatures and lower viscosities than are normally associated with the glass transition. The results are discussed in the context of several recent theories of structural relaxation in glassy liquids.
Keywords
This publication has 18 references indexed in Scilit:
- Single-crystal silicon high-Q torsional oscillatorsReview of Scientific Instruments, 1985
- Interactions, local order, and atomic-rearrangement kinetics in amorphous nickel-phosphorous alloysPhysical Review B, 1985
- Mode-coupling theory of the glass transitionPhysical Review A, 1985
- Hydrodynamic Theory of the Glass TransitionPhysical Review Letters, 1985
- Dynamics of supercooled liquids and the glass transitionJournal of Physics C: Solid State Physics, 1984
- Kinetic Ising Model of the Glass TransitionPhysical Review Letters, 1984
- Dynamical model of the liquid-glass transitionPhysical Review A, 1984
- Anomalous behavior of the thermal conductivity and the viscosity in the supercooled region as determined by mode-mode couplingPhysica A: Statistical Mechanics and its Applications, 1980
- Studies in molecular dynamics. XIV. Mass and size dependence of the binary diffusion coefficientThe Journal of Chemical Physics, 1974
- Molecular Transport in Liquids and GlassesThe Journal of Chemical Physics, 1959