Direct Measurement of Desorption Kinetics ofat Low Temperatures
- 3 May 1982
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 48 (18) , 1259-1263
- https://doi.org/10.1103/physrevlett.48.1259
Abstract
A direct method for measuring the desorption time constant of flash-desorbed films (≲ 1 monolayer), adsorbed on Nichrome or Constantan heaters, is described. A time constant is found which behaves as , where is the heater temperature. The value for the characteristic lifetime is - sec, orders of magnitude shorter than that previously reported. The measured energy parameter was found to be of the chemical potential.
Keywords
This publication has 8 references indexed in Scilit:
- Thermal desorption of gasesPublished by Elsevier ,2002
- Quantum statistical theory of flash desorptionThe Journal of Chemical Physics, 1980
- Phonon reflection at a sapphire-vacuum interfaceJournal of Physics C: Solid State Physics, 1979
- One-phonon scattering of atoms in three dimensions by a simplified continuum model of a surface: Thermal desorptionThe Journal of Chemical Physics, 1978
- Thermodynamic study of themonolayer adsorbed on GrafoilPhysical Review A, 1974
- Measurement of Lifetimes and Binding Energies of Atoms Adsorbed on Surfaces at Low Temperatures by a Rapid-Flash-Desorption TechniquePhysical Review Letters, 1973
- Phonon-Induced Desorption of Adatoms from Crystal Surfaces. II. Numerical Computations for a Model SystemPhysical Review B, 1973
- Evaporation from Superfluid HeliumPhysical Review Letters, 1972