The Ultraviolet Absorption of NO2
- 1 October 1940
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 8 (10) , 765-774
- https://doi.org/10.1063/1.1750577
Abstract
A system of eight discrete and several diffuse bands in the ultraviolet absorption spectrum of NO2 has been analyzed. From the positions of the bands and their temperature coefficient of absorption the upper state intervals have been determined as 523 and 714 cm—1, those of the lower state as 749 and 1319 cm—1. The latter are not the same as the fundamentals deduced from infra-red data. Different possibilities of reconciling these intervals are discussed.Keywords
This publication has 5 references indexed in Scilit:
- The Rotational Structure of the Hydrazoic Acid Bands in the Photographic Infra-RedThe Journal of Chemical Physics, 1940
- The Entropies of Nitrogen Tetroxide and Nitrogen Dioxide. The Heat Capacity from 15°K to the Boiling Point. The Heat of Vaporization and Vapor Pressure. The Equilibria N2O4=2NO2=2NO+O2The Journal of Chemical Physics, 1938
- Shape of the NO2 MoleculeNature, 1935
- The Infrared Absorption Spectra of Nitrogen Dioxide and TetroxideThe Journal of Chemical Physics, 1934
- The Infrared Absorption Spectra of NO2 and N2O4The Journal of Chemical Physics, 1933