The mode of olefin rotation in [Os(CO)NO(C2H4)(PPh3)2]PF6

1 January 1972

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 23,p. 1312-1313
https://doi.org/10.1039/c39720001312

Abstract

The first direct experimental evidence that indicates the axis and mode of rotation of co-ordinate olefin molecules has been obtained from variable temperature ¹H and ¹³C n.m.r. studies on the complex [Os(CO)NO(C₂H₄)(PPh₃)₂]PF₆.

Keywords

13C
AXIS
EXPERIMENTAL
N.M.R
ORDINATE
OLEFIN ROTATION