Neutron diffraction study of the structure and phase transitions of alkali cyanide crystals
- 1 June 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 66 (11) , 5147-5149
- https://doi.org/10.1063/1.433776
Abstract
The structures of sodium and potassium cyanide have been studied by neutron powder diffraction as a function of temperature between 6 and 300 K. The orientation of the CN ions in the lowest temperature phase has been established, and the mechanism of the order–disorder phase transitions has been elucidated by a careful study of a superlattice line intensity in KCN.Keywords
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