A novel diaminoborate ligand system derived from 1,8-diaminonaphthalene and 9-BBN: preparation of titanium and zirconium complexes and crystal structure of the titanium complex
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 2,p. 229-230
- https://doi.org/10.1039/a607194e
Abstract
1,8-Diaminonaphthalene reacts selectively with 1 equiv. of 9-BBN to form a bridging amine–aminoborane, and with 2 equiv. of 9-BBN to form a non-bridging bis(aminoborane); these aminoboranes give rise to a novel diaminoborate (4e,1-) ligand system by reactions with dimethylamides of titanium and zirconium.Keywords
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