Photoreactions of pyridine- and 3-bromopyridine-pentacarbonyltungsten in argon matrices at 12 K
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 696-697
- https://doi.org/10.1039/c39750000696
Abstract
Infrared spectroscopy provides evidence that 366 nm photolysis of [W(CO)5L], where L = pyridine or 3-bromopyridine, in an argon matrix at 12 K produces [W(CO)5]; the reaction is shown to be photochromic by subsequent irradiation at 435 nm.Keywords
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