Homogeneous hydrogenation of aqueous hydrogen carbonate to formate under exceedingly mild conditions—a novel possibility of carbon dioxide activation†
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 971-972
- https://doi.org/10.1039/a902368b
Abstract
Water soluble ruthenium(II)– and rhodium(I)–phosphine complexes catalyze the hydrogenation of aqueous HCO3 – to HCO2 – under mild conditions with turnover frequencies up to 262 TO h–1.Keywords
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