Co-ordination of amides to cis-[Pt II (NH3)2(H2O)2]2+
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 61-62
- https://doi.org/10.1039/c39810000061
Abstract
15 N and 195Pt n.m.r. studies show that when acetamide is added to aqueous solutions of cis-[Pt(NH3)2-(H2O)2]2+ and [Pt(en)(H2O)2]2+(en = ethylenediamine), equilibria are rapidly established with species in which H2O is substituted by the amide carbonyl oxygen atom without NH2 deprotonation; the relevance to platinum blue formation is discussed.Keywords
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