Chelation-controlled regioselective epoxide–carbonyl rearrangement: a ring enlargement route to (±)-modhephene
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1259-1260
- https://doi.org/10.1039/c39840001259
Abstract
A new formal total synthesis of (±)-modhephene (1) employing a chelation-controlled regioselective epoxide-carbonyl rearrangement as the key step is described.Keywords
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