Base-promoted rearrangement of siloxyammonium salts: a new method of dealkylation of tertiary amines via their N-oxides
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 192-193
- https://doi.org/10.1039/c39840000192
Abstract
Siloxyammonium salts prepared from tertiary amine N-oxides and trialkylsilyl trifluoromethanesulphonate undergo rearrangement in the presence of strong bases to give α-siloxyamines, which can be converted into secondary amine derivatives.Keywords
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