Crystal and molecular structures of bis{tetracarbonyldiphenylmethylphosphinemanganese(0)} and bis{tetracarbonyldimethylphenylarsinemanganese(0)}

Abstract
In the molecule [Mn2(CO)8(PMePh2)2], the phosphine ligands are attached axially, but in [Mn2(CO)8(AsMe2Ph)2] the arsine ligands are attached equatorially.

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