Structure and Magnetic Properties of a Nitroxide Diruthenium(II,III) Complex, [Ru2(O2CCMe3)4(tempo)2][Ru2(O2CCMe3)4(H2O)2](BF4)2 (tempo = 2,2,6,6-Tetramethylpiperidine-1-oxyl)
- 1 June 1995
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 68 (6) , 1647-1653
- https://doi.org/10.1246/bcsj.68.1647
Abstract
A nitroxide complex, [RU(2)(O(2)CCMe(3))(4)(tempo)(2)][Ru-2(O(2)CCMe(3))(4)(H2O)(2)](BF4)(2) (tempo = 2,2,6,6-tetramethylpiperidine-1-oxyl) has been prepared and characterized by elemental analysis, X-ray crystal structure analysis, and variable temperature magnetic susceptibility and ESR spectrum measurements. A fairly large antiferromagnetic interaction (J=-130 cm(-1)) between the diruthenium core and the nitroxide radical has been observed.This publication has 18 references indexed in Scilit:
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