Reduktion von Hydroxyketonen mit Boranen
- 5 July 1978
- journal article
- research article
- Published by Wiley in European Journal of Organic Chemistry
- Vol. 1978 (5) , 695-704
- https://doi.org/10.1002/jlac.197819780502
Abstract
Die Hydroxyketone 1–9 wurden mit Diboran, (1,1,2‐Trimethylpropyl)boran und Monochlorboran zu cis/trans‐Gemischen der entsprechenden Diole reduziert. Anhand der erhaltenen Isomerenverhältnisse wird der Einfluß der Hydroxyfunktion und der Substituentenposition auf die Stereoselektivität Reduktion untersucht.Keywords
This publication has 21 references indexed in Scilit:
- A Facile Preparation of the Ethylene Glycol Mono-Ketal of Cyclohexane-1, 4-DioneSynthetic Communications, 1974
- Asymmetric polymers. XXV. Synthesis of some optically active c‐substituted hexahydro‐2H‐azepin‐2‐onesJournal of Polymer Science Part A-1: Polymer Chemistry, 1972
- Novel addition of an alcohol to an enol ether. Isomerization of 1,4,5,6-tetrahydro-3-methoxybenzyl alcohol to 1-methoxy-7-oxabicyclo[3.2.1]octaneThe Journal of Organic Chemistry, 1972
- Selective reductions. XV. Reaction of diborane in tetrahydrofuran with selected organic compounds containing representative functional groupsJournal of the American Chemical Society, 1970
- NMR Conformational analysis of 4-hydroxycyclohexanone and 1,4-cyclohexanediols. Coupling constants averaging induced by conformational equilibria and by strong coupling effects—role of solventJournal of Pharmaceutical Sciences, 1967
- A SIMPLE PROCEDURE FOR THE CHROMIC ACID OXIDATION OF ALCOHOLS TO KETONES OF HIGH PURITYJournal of the American Chemical Society, 1961
- The Formation of Five and Six-membered Rings by the Acyloin Condensation. I. The Cyclization of Glutaric and Adipic EstersJournal of the American Chemical Society, 1950
- Über Tetrahydro‐resorcin (3‐Oxy‐cyclohexanon)Berichte der deutschen chemischen Gesellschaft (A and B Series), 1942
- Some Reactions of Δ2-Cyclohexenone, Including the Synthesis of Bicyclo(2,2,2)-octanedione-2,6Journal of the American Chemical Society, 1940
- Über die Synthese von Ketoalkoholen und mehrwertigen Alkoholen aus cyclischen Ketonen und FormaldehydBerichte der deutschen chemischen Gesellschaft (A and B Series), 1923