Rearrangement of substituted azido-1,2,3-triazolides to (α-diazoalkyl)tetrazolides
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 4,p. 785-790
- https://doi.org/10.1039/a708872h
Abstract
The scope of the title process has been studied, showing that anions 4′ having R = H, (substituted) Ph and CO2Me react cleanly (and still satisfactorily in the case R = Me), while with R = COMe, COAr and CN extensive decomposition occurs. The experimental findings (rate constants, activation parameters) have been elucidated through PM3 calculations.Keywords
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