Hydrodechlorination of chloroaromatics: the use of a bifunctional homogeneous rhodium catalyst for the conversion of chloroaromatics into saturated hydrocarbons
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 806-807
- https://doi.org/10.1039/c39920000806
Abstract
The catalytic conversion of chloroaromatics into the corresponding saturated hydrocarbons is catalysed by a bifunctional homogeneous rhodium catalyst system generated from [(C5Me5)RhCl2]2 in the presence of an excess of NEt3 under 600 psi H2 at 75 °C (1 psi ≈ 6.894757 × 103 Pa).Keywords
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- (Pentamethylcyclopentadienyl)rhodium and -iridium complexes: approaches to new types of homogeneous catalystsAccounts of Chemical Research, 1978