Radiative transition probabilities for the B 1Π–X 1Σ+ and B 1Π–A 1Σ+ bands of 7LiH

Publisher Website
Google Scholar
Abstract
The recently reported [J. Chem. Phys. 66, 5412 (1977)] hybrid potential curves for the X 1Σ+ and A 1Σ+ states of LiH and the herein reported hybrid potential curve for the B 1Π state of LiH are combined with the ab initio transition moments of Docken and Hinze [J. Chem. Phys. 57, 4936 (1972)] to calculate radiative transition probabilities between all B 1Π (v′?2) and all X 1Σ+ (v″?23) and A 1Σ+ (v″?26) vibrational levels of 7LiH. The strongest single emission band found is the B 1Π (v′=2) →X 1Σ+ (v″=23) band between the highest ’’long‐range’’ levels in each potential. For all B 1Π levels the emission is dominated by B→X rather than B→A emission.

This publication has 13 references indexed in Scilit: