Study of bis(n-Propylsulfinyl)Ethane Copper(II) Complexes
- 1 April 1992
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 22 (4) , 363-370
- https://doi.org/10.1080/15533179208020470
Abstract
Eight copper(II) complexes were prepared by reacting CuX2(X = ClO4 −, NO3 −, Cl− and Br−) with meso(a) and rac (β) isomers of bis (propylsufinyl)ethane. The complexes have been characterized by elemental analyses, infrared spectra and magnetic studies. In all cases, the copper ion bonds to the sulfoxide noiety via the oxygen atom. The configuration of the complexes may be D4h. From the e.s.r. spectra of Cu(a-L)2 < ClO4)2, Cu(β -L)2(ClO4)2 and Cu(a-L)Cl2 (g∥ = 2.404, 2.326 and 2.325 respectively), it appears that Cu-L bonds are ionic.Keywords
This publication has 4 references indexed in Scilit:
- Complexes of first row transition metals withMeso-1,2-bis(propylsulphinyl)ethaneTransition Metal Chemistry, 1985
- Electron spin resonance studies on complexes of Copper(II) with o-phenolic oximesPolyhedron, 1982
- The myth of the non-coordinating anionJournal of Chemical Education, 1973
- The use of conductivity measurements in organic solvents for the characterisation of coordination compoundsCoordination Chemistry Reviews, 1971