Multiple carbon–carbon bond cleavage on a heptaosmium cluster: synthesis and molecular structure of [Os7(CO)15(µ3-CPh)4]
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 972-973
- https://doi.org/10.1039/c39880000972
Abstract
The heptaosmium cluster [H2Os7(CO)20] reacts with Ph2C2 to yield the organometallic cluster [Os7(CO)15(µ3-CPh)4], which has been shown by X-ray crystallographic analysis to possess an unprecedented metal core geometry based on a bicapped square pyramidal arrangement of osmium atoms.Keywords
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