Simple, high yield syntheses of heterobimetallic complexes of Ph2PCH2PPh2(dppm) with platinum, mercury, and silver
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1240-1241
- https://doi.org/10.1039/c39820001240
Abstract
Treatment of the readily available salts [Pt(dppm)2]2X (dppm = Ph2PCH2PPh2) with (i) Hg(CCR)2 or (ii) Hg(OAc)+ RCCH or (iii) Hg(CN)2 gives virtually quantitative yields of Y2Pt(µ-dppm)2 HgX2(Y = CCR or CN, R = Ph, p-tolyl, Me, or Prn, X = Cl) and with AgOAc + PhCCH, high yields of (PhCC)2Pt(µ-dppm)2AgX (X = Cl or I).Keywords
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