Phosphoranaloge von Aminosäuren II1. Synthese von α-Aminophosphonsäuren und α-Aminophosphinsäuren, ausgehend von den entsprechendenN-Acylimino-Derivaten
- 1 January 1989
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1989 (02) , 97-101
- https://doi.org/10.1055/s-1989-27162
Abstract
Synthesis of α-Amino Phosphonic Acids and α-Amino Phosphinic Acids via the Corresponding N-Acylimino Derivatives Acyliminomethylphosphonic and acyliminomethylphosphinic esters, usually formed in situ from the corresponding acylamino(bromo)methyl compounds, react with higher order mixed cuprates to yield, after hydrolysis, C-substituted aminomethylphosphonic acids and aminomethylphosphinic acids, respectively.Keywords
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