Anti-Markownikoff 1,2-hydrosulphonylation of 1,3-dienes viaπ-allylpalladium complexes
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 367b-368
- https://doi.org/10.1039/c3978000367b
Abstract
The reaction of palladium(II) chloride with 1,3-dienes and sodium alkanesulphinates in acetic acid produces di-µ-chloro-bis(1-syn-alkylsulphonylmethyl-π-allyl)dipalladium(II) complexes, which on treatment with dimethylglyoxime in methanol are degradated selectively to γδ-unsaturated sulphone.Keywords
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